HP Labs
has made a nano-scale device which stores data, explains previous
anomalies in nano-device characteristics, and may be able to act as
a synapse in analogue neural networks. It is also the first
physical implementation of the memristor,
claims HP, a theoretical partner to resistors, capacitors and
inductors invented in 1971.
"Transistors are slightly faster at switching, but this is
fast," HP Labs spokesman David Harrah told Electronics Weekly.
"Stan [research head Stan Williams] is talking in terms of taking
it down to 14nm and possibly single digits, so it has the potential
to go to 1Tbit/cm2."
Possible in several ionic-electronic systems, the
metal-insulator-metal device demonstrated has a stack of two
titanium oxide layers its insulator. One is doped with oxygen, the
other slightly starved of oxygen.
Electrons flow first through one layer and then the other. "The
oxygen creates vacancies and these vacancies migrate to the other
layer with current flow," said Harrah.
That is: the oxygen ions move, causing the boundary between
oxygen-rich and oxygen-starved TiO2 to move towards one
electrode or the other changing the overall resistance of the
insulator layer.
Depending on current direction, resistance increases with time
or decreases with time, with the magnitude of resistance change
dependent on charge (current x time). When current flow stops,
resistance freezes. When current is reversed, resistance change
reverses.
Plotted, current and voltage form a hysteresis loop which can be
frozen at any point by stopping current flow and the device can
therefore store data.
According to research head Williams, this behaviour is only
noticeable in nano-scale dielectric layers as these offer the huge
potential gradients required to shift ions at reasonable
voltages.
Realising that ion drift in insulators can cause hysteresis may
explain previously nano-scale electrical anomalies.
"The rich hysteretic I-V characteristics detected in many thin
film two-terminal devices can now be understood," Williams told the
journal Nature.
HP also sees the junction as possible component of artificial
brains. "It is very similar to a brain synapse," said spokesman
Harrah. "You could simulate a brain with transistors as neurons and
a bunch of these as synapses."
37 years ago, scientist Leon Chua, now at the University of
California at Berkeley, mused theoretically that with: resistors
linking current and voltage, capacitors linking voltage and charge,
and inductors linking current and flux there should be a component
that linked charge and flux.
He named it a memristor - where memristance(M) links the two
like this: d(flux)=Md(charge).
"In the trivial case of linear elements in which M is a
constant, memristance is identical to resistance, and thus of no
special interest," Williams told the journal Nature. "However, if M
is itself a function of charge to yield a nonlinear circuit
element, then things become quite interesting."
For limited excursions, Williams' device is exactly a memristor,
said HP.
"This is an amazing development," Chua said. "It took someone
like Stan Williams with a multi-disciplinary background and deep
insights to conceive of such a tiny memristor only a few atoms in
thickness."


Atomic force microscope images of 17 HP Labs non-linear
devices in a row, each a pair of oxide layers between the single
bottom wire and one of the top wires. "The devices act as 'memory
resistors' [memristors], with the resistance of each device
depending on the amount of charge that has moved through each one,"
Stanley Williams director of HP's quantum systems lab, told
Electronics Weekly. The wires are 50nm - about 150 atoms -
wide.